Bon, Volodymyr2024-06-202024-06-202024-07-172024-06-20https://opara.zih.tu-dresden.de//handle/123456789/709https://doi.org/10.25532/OPARA-518The approach of multivariate MOFs was used to fine-tune the mechanical properties of the flexible framework DUT-49. In situ XRD, NMR and physisorption studies showed that the partial incorporation of a more rigid linker into DUT-49 framework enables a stabilization of the metastable open pore phase which led to a twofold amplification of the expelled gas amount upon “Negative Gas Adsorption” transition.Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/3::31::322::322-01