Browsing by Author "Richter, Julia"

Filter results by typing the first few letters
Now showing 1 - 2 of 2
  • ItemPublic Metadata
    GRK 2802: Extra-carbonization of biochar pellets obtained after co-torrefaction and co-pyrolysis with bituminous coal
    (Technische Universität Bergakademie Freiberg, 2025-11-28) Koveria, Andrii; Zuber, Jan; Himcinschi, Cameliu; Vogt, Carla; Richter, Julia
    The paper investigates the chemical and structural changes in biochar pellets resulting from the co-torrefaction and co-pyrolysis of pine wood (Pinus sylvestris) pellets with bituminous coal at a 1:1 ratio at 300, 500, and 700 °C. At 500 °C co-pyrolysis, noticeable changes occur in biochar during co-treatment with coal, as observed by Fourier-transform infrared spectroscopy (FT-IR), graphite-assisted laser desorption/ionization-Fourier transform ion cyclotron resonance mass spectrometry (GALDI-FT-ICR-MS), and Raman spectroscopy compared to individual pyrolysis. Proximate and ultimate analyses show an increase in carbon content and decreases in volatile matter, oxygen, and hydrogen in co-treated biochar pellets. FT-IR and van Krevelen plots indicate compounds with lower O/C ratios and fewer oxygen-rich functionalities. Raman spectroscopy shows that, at 300 and 500 °C, co-pyrolyzed biochar pellets have slightly more structural ordering and less disorder than biochar pellets from individual pyrolysis. This suggests that co-processing allows the creation of a more ordered aromatic carbon structure. GALDI-FT-ICR-MS indicates an increase in condensed aromatic hydrocarbons at the expense of lignin-like and oxygen-rich structures compared with individual pyrolysis. Specifically, 500 °C co-pyrolysis shifts biochar pellets composition toward lower O/C ratios (0–0.3); products are enriched in condensed aromatic hydrocarbons and occupy van Krevelen regions with low O/C (0–0.2) and H/C (0.4–0.8). The results demonstrate extra-carbonization effects in biochar pellets during co-pyrolysis with bituminous coal at 500 and 700 °C.
  • ItemPublic Metadata
    GRK 2802: Raman Spectroscopic Identi cation of Oxide Phases in a Cor- roded MgO-Steel Composite Anode Used in Aluminum Molten Salt Electrolysis
    (Technische Universität Bergakademie Freiberg, 2026-03-04) Drechsler, Felix; Yaroshevskyi, Serhii; Adamczyk, Alexander; Mehdizadehlima, Mahnaz; Richter, Julia; Himcinschi, Cameliu; Rafaja, David; Charitos, Alexandros; Aneziris, Christos G.; Kortus, Jens
    This study presents the post-mortem phase characterization of a metal ceramic composite anode composed of 316L stainless steel and recycled MgO, sourced from spent refractory lining bricks, employed in aluminium molten salt electrolysis. The analysis focused on the immersed section of the anode, where direct exposure to the molten Na-cryolite melt promotes the formation of corrosion products. Raman spectroscopy was applied as a structural characterization technique, providing phase information that complements the morphological and elemental analyses obtained from SEM EDX measurements. Due to its high spatial resolution, micro-Raman spectroscopy enabled the identi cation of local phases within the corrosion layer and the determination of their depth-dependent distribution. The local chemical analysis revealed an outer Fe O-rich layer penetrating several tens of micrometers into the material, followed by a Fe Al O-containing zone. Raman spectroscopy identi ed the Fe O layer as magnetite (Fe3O4) and the inner layer as hercynite (FeAl2O4), with a transition region consisting of Al-doped Fe3O4. The results demonstrate the applicability of Raman spectroscopy for identifying corrosion products to provide contributions to the corrosion mechanisms of MgO-steel anodes under electrolytic conditions.