GRK 2802: Phosphorus Partition Between Liquid Crude Steel and High-Basicity Basic Oxygen Furnace Slags Containing V2O5

Abstract

The influence of V2O5 on the phosphorus partition between liquid crude steel and heterogenous basic oxygen furnace (BOF) slag with CaO/SiO2 = 4.2 was investigated at a temperature of 1600 C in a middle frequency induction furnace. Thereby the phosphorus transfer from ‘‘steel to slag’’ as well as from ‘‘slag to steel’’ was studied over a holding time of 60 minutes. The measured results were shown as phosphorus partition and phosphorus capacity and compared with the experimental values from the literature. It was found that V2O5 in highly basic BOF slags decreases phosphorus partition and phosphorus capacity. In addition, the resulting slags were investigated using a scanning electron microscope (SEM).