Multiple superconducting transitions in Yb$_{3+x}$Co$_4$Sn$_{13-x}$

Type of the data
datacite.resourceTypeGeneral

Dataset

Total size of the dataset
datacite.size

2423040

Author
dc.contributor.author

Meret, Orlob

Author
dc.contributor.author

Levytskyi, Volodymyr

Author
dc.contributor.author

Tsirlin, Alexander

Author
dc.contributor.author

Kundys, Bohdan

Author
dc.contributor.author

Sturm, Elena

Author
dc.contributor.author

Leithe-Jasper, Andreas

Author
dc.contributor.author

Gumeniuk, Roman

Upload date
dc.date.accessioned

2025-07-31T15:18:35Z

Publication date
dc.date.available

2025-07-31T15:18:35Z

Data of data creation
dc.date.created

2025-07-22

Publication date
dc.date.issued

2025-07-31

Abstract of the dataset
dc.description.abstract

Abstract of the accompanying article: In the Yb-Co-Sn system a Remeika phase Yb$_{3+x}$Co$_{4}$Sn$_{13-x}$ is found with solid solution extending within $0\le\,x\,\le0.5$. All these compounds crystallize with primitive cubic [space group $Pm\bar{3}n$, $a\approx9.54$ \AA] strongly disordered Sc$_{3}$Ir$_4$Si$_{13+x}$ type. Stoichiometric Yb$_3$Co$_4$Sn$_{13}$ is a superconductor with critical temperature $T_c\,=\,3.1(2)$\,K, lower- [$B_\mathrm{c1}=1.90(2)$\,mT] and upper [$B_\mathrm{c2}=2.16(5)$\,T] critical fields. The specific heat jump $\Delta c_p/\gamma T_c\,=\,1.72(9)$ together with the fact that $B_\mathrm{c2}(T_c)$ dependence is described by the Werthamer-Helfand-Hohenberg (WHH) model hint towards a conventional mechanism with a weak electron-phonon coupling. Although a more precise analysis is hampered by the presence of multiple superconducting transitions observed in the specific heat of this Remeika phase, the non-stoichiometric Yb$_{3.2}$Co$_4$Sn$_{12.8}$ reveals $T_c\,=\,2.4(2)$\,K and $B_\mathrm{c2}=4.79(9)$\,T exceeding the classical Pauli limit. Strong electron-phonon coupling in this superconductor is confirmed by the high value of the $\lambda_\mathrm{AD}=0.92(2)$ parameter determined from the Allen-Dynes formula. However, the electronic specific heat of Yb$_{3.2}$Co$_4$Sn$_{12.8}$ follows the exponential law [$c_\mathrm{el}(T)\propto e^{-\Delta(0)/k_\mathrm{B}T}$] and can be described by the $\alpha$-model [$\alpha\equiv\Delta(0)/k_\mathrm{B}T_c=2$] indicating this stannide to be a conventional BCS-superconductor. Both Yb$_{3+x}$Co$_{4}$Sn$_{13-x}$ ($x=0, 0.2$) compounds reveal complex phonon spectra with possible `rattling' behavior. They are also found to be metallic systems, some aspects of which can be described by a free electron gas model.

Public reference to this page
dc.identifier.uri

https://opara.zih.tu-dresden.de/handle/123456789/1589

Public reference to this page
dc.identifier.uri

https://doi.org/10.25532/OPARA-899

Publisher
dc.publisher

Technische Universität Bergakademie Freiberg

Licence
dc.rights

Attribution 4.0 Internationalen

URI of the licence text
dc.rights.uri

http://creativecommons.org/licenses/by/4.0/

Specification of the discipline(s)
dc.subject.classification

3::32::307

Title of the dataset
dc.title

Multiple superconducting transitions in Yb$_{3+x}$Co$_4$Sn$_{13-x}$

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