Data Underpinning: Disorder-driven magnetic duality in the spin-½ system ktenasite, Cu₂.₇Zn₂.₃(SO₄)₂(OH)₆·6H₂O

Documentation of the data
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Description of the data
datacite.resourceType

Data Underpinning: Disorder-driven magnetic duality in the spin-½ system ktenasite, Cu₂.₇Zn₂.₃(SO₄)₂(OH)₆·6H₂O. Contains or describes data from: specific heat, magnetization, AC susceptometry, x-ray diffraction, SEM/EDX, FTIR, optical microscopy, DSC-TG, and neutron powder diffraction.

Type of the data
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Dataset

Total size of the dataset
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21028122

Author
dc.contributor.author

Parui, Kaushick K.

Author
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Kulbakov, Anton A.

Author
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Gumeniuk, Roman

Author
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Carrillo-Aravena, Eduardo

Author
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Fernández-Díaz, María Teresa

Author
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Savvin, Stanislav

Author
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Korshunov, Artem

Author
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Granovsky, Sergey

Author
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Doert, Thomas

Author
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Inosov, Dmytro S.

Author
dc.contributor.author

Peets, Darren C.

Upload date
dc.date.accessioned

2025-10-17T14:15:19Z

Publication date
dc.date.available

2025-10-17T14:15:19Z

Publication date
dc.date.issued

2025-10-17

Abstract of the dataset
dc.description.abstract

Article abstract: Disorder in frustrated quantum systems can critically influence their magnetic ground states and drive exotic magnetic behavior. In the S = ½ system ktenasite, Cu₂.₇Zn₂.₃(SO₄)₂(OH)₆·6H₂O, we show that structural disorder drives an unexpected dimensional crossover and stabilizes a rare coexistence of distinct magnetic states. Neutron diffraction reveals significant Cu/Zn mixing at the Cu2 site, which tunes the Cu²⁺ sublattice from a two-dimensional scalene-distorted triangular lattice into a one-dimensional spin-chain network. Magnetic susceptibility, neutron diffraction, ac susceptibility, and specific heat measurements collectively indicate magnetic duality: a coexistence of incommensurate long-range magnetic order below TN = 4 K and a cluster spin-glass state with Tf = 3.28 K at f = 10 Hz. Our findings highlight ktenasite as a rare platform where structural disorder tunes the effective dimensionality and stabilizes coexisting ordered and glassy magnetic phases, offering a unique opportunity to explore the interplay of frustration, disorder, and dimensional crossover in quantum magnets.

Public reference to this page
dc.identifier.uri

https://opara.zih.tu-dresden.de/handle/123456789/1570

Public reference to this page
dc.identifier.uri

https://doi.org/10.25532/OPARA-890

Publisher
dc.publisher

Technische Universität Dresden

Licence
dc.rights

Attribution 4.0 Internationalen

URI of the licence text
dc.rights.uri

http://creativecommons.org/licenses/by/4.0/

Specification of the discipline(s)
dc.subject.classification

3::32::307::307-01

Specification of the discipline(s)
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3::31::322::322-01

Title of the dataset
dc.title

Data Underpinning: Disorder-driven magnetic duality in the spin-½ system ktenasite, Cu₂.₇Zn₂.₃(SO₄)₂(OH)₆·6H₂O

Underlying research object
opara.descriptionObject.PhysicalObject

synthetic ktenasite powder

Public project website(s)
opara.project.publicReference

https://www.ctqmat.de

Public project website(s)
opara.project.publicReference

https://fis.tu-dresden.de/portal/en/organisations/clusters-of-excellence-ctqmat-complexity-and-topology-in-quantum-matter(7bac147f-30fb-409f-ada3-5381707258b2).html

Public project website(s)
opara.project.publicReference

https://tu-dresden.de/mn/physik/sfb1143

Project title
opara.project.title

Cluster of Excellence 2147, ct.qmat–Complexity and Topology in Quantum Matter; Correlated Magnetism: From Frustration to Topology (SFB 1143); Frustrated Magnetism in Copper Minerals (PE 3318/2-1, PE 3318/2-2); Correlated Proton Disorder and Frustrated Magnetism in Hydroxide Perovskites (IN 209/12-1, DO 590/11-1)

Files

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Gzipped tar archive of the ktenasite data

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