GRK 2802: Characterization of MgO-C recyclate and commercial MgO-C refractory bricks with and without Recyclate

Abstract

In light of the increasing focus on the recycling of refractories, the properties of commercial MgO-C refractory bricks containing MgO-C recyclate are of significant economic and ecological importance. In the present study, MgO-C recyclate and two commercially available MgO-C bricks – one grade consisting exclusively of fresh raw materials while the other containing 47.5 wt.% MgO-C recyclate – were comprehensively characterized. This involved the use of X-ray computed tomography, scanning electron microscopy, X ray fluorescence analysis, X-ray diffraction, as well as density and porosity measurements. The MgO C recyclate exhibited a heterogeneous composition consisting of MgO aggregates and contained an increased content of impurities compared to fresh MgO raw materials. The incorporation of MgO C recyclate as a raw material for commercial MgO-C bricks resulted in a decrease of the average MgO aggregate size, a higher porosity with a decrease in the median pore size and a reduced CaO/SiO2 ratio of the corresponding MgO-C brick grade. Furthermore, the MgO-C grade with 47.5 wt.% MgO-C recyclate exhibited a higher cold crushing strength, but a reduced oxidation resistance.