GRK 2802: Interactions between Molten High-Silicon Electrical Steels and Carbon-Bonded MgO Refractories Based on Recyclates

References to related material
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https://doi.org/10.1002/adem.202502160

Type of the data
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Dataset

Type of the data
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Image

Total size of the dataset
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75583570

Author
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Neubert, Lukas

Author
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Bellé, Matheus Roberto

Author
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Yehorov, Anton

Author
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Mospan, Anhelina

Author
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Stadtmüller, Till M. J.

Author
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Sridhar, Seetharaman

Author
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Aneziris, Christos G.

Author
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Volkova, Olena

Upload date
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2026-05-29T06:08:06Z

Publication date
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2026-05-29T06:08:06Z

Publication date
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2026-05-29

Abstract of the dataset
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In the present study a comprehensive investigation of the interactions between different molten high-silicon electrical steels (3 to 6 mass-% silicon) in aluminum killed condition with conventional and recycled MgO–C refractories is conducted. Immersion tests are carried out in accordance with the standards for testing and assessment of corrosion of refractories by liquids (DIN CEN/TS 15 418). Various mechanisms are defined and described which determine the corrosion of the refractory material in addition to infiltration. Scanning electron microscopy including energy dispersive X-ray spectroscopy (EDX analysis) is conducted to identify wear reactions, material transfers and reaction products at the contact zones and in the infiltration layers. The theoretically possible infiltration length is calculated and the limited applicability of the equations known from the literature is discussed. The formation of calcium sulfides and on other crucible reactions that take place are considered. These provide information and at the same time they influence the interactions between refractory materials and liquid steel.

Public reference to this page
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https://opara.zih.tu-dresden.de/handle/123456789/2421

Publisher
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Technische Universität Bergakademie Freiberg

Specification of the discipline(s)
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4::43

Title of the dataset
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GRK 2802: Interactions between Molten High-Silicon Electrical Steels and Carbon-Bonded MgO Refractories Based on Recyclates

Project abstract
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The focus of this doctoral project is to investigate the interaction of electrical steels (transformer steels), with high-silicate purity ladle slags free of running slag, with MgO-C products based on recyclates and environmentally friendly binders. The formation of ladle glaze can be studied by immersing a MgO-C product in a tracer-labelled slag during an immersion test. Investigations of the thermophysical properties of the liquid, killed/unkilled electrical steels and liquid slag as a function of temperature and SiO2 content, combined with thermodynamic calculations using FactSage software, make it possible to determine their influence on the interaction with MgO-C and ladle glaze formation. The influence of ladle glaze on the oxidic inclusion population, on the pick-up effect (undesirable increase of alloying elements) and reoxidation of the alloying elements is investigated by ladle glaze dissolution in the electric steel melt accompanied by chemical analysis and optical microscopy in combination with AFA (Automatic Feature Analysis) in the P-SEM. Research into the effect of the oxidic, non-metallic inclusions that form from ladle glaze on clogging in the spout nozzle based on recycled Al2O3-C is another focus.

Funding Acknowledgement
opara.project.fundingAcknowledgement

The dataset was generated within the framework of the Research Training Group GRK 2802 (project ID: 461482547) funded by the German Research Foundation (DFG).

Public project website(s)
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https://tu-freiberg.de/en/research/grk2802

Project title
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GRK2802_P4_Interaction of electrical steels with MgO-C products based on recyclates and environmentally friendly binders

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