GRK 2802: Steel ceramic composite anodes based on recycled MgO–C lining bricks for applications in cryolite/aluminum melts

References to related material
datacite.relatedItem.IsSupplementTo

https://doi.org/10.1016/j.oceram.2023.100458

Type of the data
datacite.resourceTypeGeneral

Dataset

Total size of the dataset
datacite.size

69420796

Author
dc.contributor.author

Yaroshevskyi, Serhii

Author
dc.contributor.author

Weigelt, Christian

Author
dc.contributor.author

Malczyk, Piotr

Author
dc.contributor.author

Roungos, Vasileios

Author
dc.contributor.author

Hubalkova, Jana

Author
dc.contributor.author

Zienert, Tilo

Author
dc.contributor.author

Kraft, Bastian

Author
dc.contributor.author

Wagner, Stefan

Author
dc.contributor.author

Aneziris, Christos

Upload date
dc.date.accessioned

2026-02-16T18:10:12Z

Publication date
dc.date.available

2026-02-16T18:10:12Z

Publication date
dc.date.issued

2026-02-16

Abstract of the dataset
dc.description.abstract

Novel manufacturing route for composite inert anodes containing 60:40 of 316 L stainless steel and MgO powder obtained from recycled MgO-C brick material has been developed and evaluated. After burnout of residual carbon from the recycled MgO-C powder, MgO and steel were granulated and pre-sintered in order to generate agglomerates of composite material acting as coarse grains within the composite material, and thus lowering the sintering-related shrinkage. The pre-sintered granules were mixed with raw steel and MgO powder in order to achieve a high particle packing and subsequently cold isostatically pressed in the form of electrodes. All manufactured anode samples were subjected to sintering at 1350 ◦C and pre-oxidation at different temperatures – 800 °C, 900 °C, and 1000 °C. Afterwards, mechanical and electrical properties of the manufactured electrodes were characterized. The results show that upcycling of the MgO-C material enables manufacturing of sophisticated electrode products, which can be applied in the aluminum industry.

Public reference to this page
dc.identifier.uri

https://opara.zih.tu-dresden.de/handle/123456789/2077

Publisher
dc.publisher

Technische Universität Bergakademie Freiberg

Specification of the discipline(s)
dc.subject.classification

4::43::405::405-05

Specification of the discipline(s)
dc.subject.classification

4::43

Title of the dataset
dc.title

GRK 2802: Steel ceramic composite anodes based on recycled MgO–C lining bricks for applications in cryolite/aluminum melts

Project abstract
opara.project.description

This research aims to investigate the potential of upcycling spent MgO-C refractories as a ceramic feedstock for steel-ceramic composite materials intended for application as carbonless anodes in aluminium electrolysis. The work focuses on developing a reproducible processing route for recyclate-based MgO-steel composites and on establishing structure-processing relationships relevant to electrochemical operation in cryolitic environments. Particular attention is given to the controlled pre-oxidation treatments, and phase evolution on electrical conductivity of the composite material and chemical interaction with the electrolyte. Through systematic materials characterization and electrochemical exposure under laboratory conditions, the project seeks to identify the key degradation mechanisms governing composite anode behaviour and to delineate the design constraints and opportunities for integrating refractory recycling strategies into inert-anode development.

Funding Acknowledgement
opara.project.fundingAcknowledgement

The dataset was generated within the framework of the Research Training Group GRK 2802 (project ID: 461482547) funded by the German Research Foundation (DFG).

Public project website(s)
opara.project.publicReference

https://tu-freiberg.de/en/research/grk2802

Project title
opara.project.title

GRK2802_P7_Metalloceramic composites made from MgO or MgO-C recyclates in combination with steel and other additives as inert or low-carbon anodes in aluminium fused-salt electrolysis

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