GRK 2802: Effect of Oxygen on Thermophysical Properties of Molten High-Silicon Electrical Steels and Its Impact on Bubble Formation Behavior

References to related material
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https://doi.org/10.1007/s11663-025-03594-9

Type of the data
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Dataset

Type of the data
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Image

Total size of the dataset
datacite.size

32820180

Author
dc.contributor.author

Neubert, Lukas

Author
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Bellé, Matheus Roberto

Author
dc.contributor.author

Seetharaman, Sridhar

Author
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Volkova, Olena

Upload date
dc.date.accessioned

2025-10-24T12:02:05Z

Publication date
dc.date.available

2025-10-24T12:02:05Z

Publication date
dc.date.issued

2025-10-24

Abstract of the dataset
dc.description.abstract

The presence of oxygen in liquid steels has a considerable influence on their properties. Higher oxygen concentrations are typical for unkilled melts, after tapping from the basic oxygen furnace (BOF) or during secondary metallurgy. This influences thermophysical properties, for instance, surface tension, due to the surface activity of dissolved oxygen. Processes in secondary metallurgy or the interaction of the melt with the refractory material will be different. In this study, density and surface tension of molten high-silicon electrical steels are analyzed dependent of different oxygen contents, which are comparable to industrial melts during secondary metallurgy. The maximum bubble pressure method was used, and total oxygen contents between 77 and 300 ppm were taken into consideration. The silicon content of the steels is varied between 3 and 6 mass-pct. The effect of oxygen on the bubble formation behavior during decarburization in a liquid steel melt is also discussed. The results make it possible to calculate the size of bubbles that form in a melt. These findings are transferred to the processing of electrical steels, to vacuum treatments like the RH or VOD process. Reactions such as decarburization and the dissolution behavior of alloying agents are described more precisely based on these insights.

Public reference to this page
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https://opara.zih.tu-dresden.de/handle/123456789/1724

Publisher
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Technische Universität Bergakademie Freiberg

Specification of the discipline(s)
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4::43

Title of the dataset
dc.title

GRK 2802: Effect of Oxygen on Thermophysical Properties of Molten High-Silicon Electrical Steels and Its Impact on Bubble Formation Behavior

Project abstract
opara.project.description

The focus of this doctoral project is to investigate the interaction of electrical steels (transformer steels), with high-silicate purity ladle slags free of running slag, with MgO-C products based on recyclates and environmentally friendly binders. The formation of ladle glaze can be studied by immersing a MgO-C product in a tracer-labelled slag during an immersion test. Investigations of the thermophysical properties of the liquid, killed/unkilled electrical steels and liquid slag as a function of temperature and SiO2 content, combined with thermodynamic calculations using FactSage software, make it possible to determine their influence on the interaction with MgO-C and ladle glaze formation. The influence of ladle glaze on the oxidic inclusion population, on the pick-up effect (undesirable increase of alloying elements) and reoxidation of the alloying elements is investigated by ladle glaze dissolution in the electric steel melt accompanied by chemical analysis and optical microscopy in combination with AFA (Automatic Feature Analysis) in the P-SEM. Research into the effect of the oxidic, non-metallic inclusions that form from ladle glaze on clogging in the spout nozzle based on recycled Al2O3-C is another focus.

Funding Acknowledgement
opara.project.fundingAcknowledgement

The dataset was generated within the framework of the Research Training Group GRK 2802 (project ID: 461482547) funded by the German Research Foundation (DFG).

Public project website(s)
opara.project.publicReference

https://tu-freiberg.de/en/research/grk2802

Project title
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GRK2802_P4_Interaction of electrical steels with MgO-C products based on recyclates and environmentally friendly binders

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