Data Underpinning: Stacking Disorder in Novel ABAC-Stacked Brochantite

Documentation of the data
datacite.description.TechnicalInfo

Each measurement technique has its own subdirectory, and each of these subdirectories contains a notes.txt file with further details.

Description of the data
datacite.resourceType

Data underpinning "Disordered ground state in the 3D face-centred frustrated spin-5/2 system MnSn(OH)₆". Contains or describes data from: -specific heat -magnetization -x-ray powder diffraction -x-ray single-crystal diffraction -neutron Laue diffraction -optical microscopy -X-ray diffuse scattering

Type of the data
datacite.resourceTypeGeneral

Dataset

Total size of the dataset
datacite.size

1252632731

Author
dc.contributor.author

Mannathanath Chakkingal, Aswathi

Author
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Fuller, Chloe

Author
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Avdeev, Maxim

Author
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Gumeniuk, Roman

Author
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Rahn, Marein C.

Author
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Pabst, Falk

Author
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Wang, Yiran

Author
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Granovsky, Sergey

Author
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Chernyshov, Dmitry

Author
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Inosov, Dmytro S.

Author
dc.contributor.author

Peets, Darren C.

Upload date
dc.date.accessioned

2025-01-16T15:05:47Z

Publication date
dc.date.available

2025-01-16T15:05:47Z

Publication date
dc.date.issued

2025-01-16

Abstract of the dataset
dc.description.abstract

Abstract of the accompanying article: In geometrically frustrated magnetic systems, weak interactions or slight changes to the structure can tip the delicate balance of exchange interactions, sending the system into a different ground state. Brochantite, Cu₄SO₄(OH)₆, has a copper sublattice composed of distorted triangles, making it a likely host for frustrated magnetism, but exhibits stacking disorder. The lack of synthetic single crystals has limited research on the magnetism in brochantite to powders and natural mineral crystals. We grew crystals which we find to be a new polytype with a tendency toward ABAC stacking and some anion disorder, alongside the expected stacking disorder. Comparison to previous results on natural mineral specimens suggests that cation disorder is more deleterious to the magnetism than anion and stacking disorder. Our specific heat data suggest a double transition on cooling into the magnetically ordered state.

Public reference to this page
dc.identifier.uri

https://opara.zih.tu-dresden.de/handle/123456789/1179

Public reference to this page
dc.identifier.uri

https://doi.org/10.25532/OPARA-701

Publisher
dc.publisher

Technische Universität Dresden

Licence
dc.rights

Attribution 4.0 Internationalen

URI of the licence text
dc.rights.uri

http://creativecommons.org/licenses/by/4.0/

Specification of the discipline(s)
dc.subject.classification

3::32::307::307-01

Specification of the discipline(s)
dc.subject.classification

3::31::322::322-01

Title of the dataset
dc.title

Data Underpinning: Stacking Disorder in Novel ABAC-Stacked Brochantite

Underlying research object
opara.descriptionObject.Substance

Synthetic brochantite single crystals

Public project website(s)
opara.project.publicReference

https://www.ctqmat.de

Public project website(s)
opara.project.publicReference

https://fis.tu-dresden.de/portal/en/organisations/clusters-of-excellence-ctqmat-complexity-and-topology-in-quantum-matter(7bac147f-30fb-409f-ada3-5381707258b2).html

Public project website(s)
opara.project.publicReference

https://tu-dresden.de/mn/physik/sfb1143

Project title
opara.project.title

Cluster of Excellence 2147, ct.qmat–Complexity and Topology in Quantum Matter; Correlated Magnetism: From Frustration to Topology (SFB 1143); Frustrated Magnetism in Copper Hydroxysulphate Minerals (PE 3318/2-1)
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